A type of primary voltaic cell with a copper positive electrode and a negative electrode of a zinc amalgam. Invented in 1836 by the British chemist John Daniell (1790 -1845).

The zinc amalgam electrode is placed in an electrolyte of dilute sulphuric acid or zinc sulphate solution in a porous pot, which stands in a solution of copper sulphate in which the copper electrode is immersed. While the reaction takes place, ions move through the porous pot, but when it is not in use, the cell should be dismantled to prevent the diffusion of one electrolyte into the other.

The e.m.f of the cell is 1.08 volts with sulphuric acid and 1.1 volts with zinc sulphate.